RuCl2[(S)-xylbinap][(S,S)-dpen] - Names and Identifiers
Name | Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
|
Synonyms | RuCl2[(S)-xylbinap][(S,S)-dpen] RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] -binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[( Dichloro[(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(S,S)-1,2-diphenylethylenediamine]ruthenium(II) Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) DICHLORO{(S)-(-)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[( Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen]
|
CAS | 220114-03-4
|
RuCl2[(S)-xylbinap][(S,S)-dpen] - Physico-chemical Properties
Molecular Formula | C66H64Cl2N2P2Ru
|
Molar Mass | 1119.15 |
Appearance | Powder |
Color | yellow |
Storage Condition | 2-8°C |
Sensitive | air sensitive |
RuCl2[(S)-xylbinap][(S,S)-dpen] - Risk and Safety
RuCl2[(S)-xylbinap][(S,S)-dpen] - Introduction
Dichloro{(S)-(-)-2,2 '-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) is an organometallic complex with the chemical formula Cl {(S)-(-)-BINAP}[(1S,2S)-(-)-DPEN]Ru(II), where BINAP is 2,2 '-BIS [BIS (3,5-xylyl) phosphine]-1,1'-Binaphthyl, DPEN is 1,2-diphenylethylenediamine.
The properties of this complex are as follows:
1. Appearance: colorless crystal or white powder;
2. Solubility: soluble in common organic solvents (such as dichloromethane, toluene, etc.);
3. Melting Point: about 100-110 ℃.
This complex has important applications in chemical synthesis and catalytic reactions:
1. As a catalyst: can be used in various organic synthesis reactions, such as asymmetric hydrogenation and disproportionation reactions;
2. Electrochemical application: can be used for asymmetric electrosynthesis reaction, electrochemical synthesis, etc.
The method of preparing the complex is obtained by the reaction of the ligand and the metal salt:
1. The ligands BINAP and DPEN react with metal salts of ruthenium (II) to form complexes.
Regarding the safety information of the substance, because the chemical substance has a certain degree of danger, the following matters should be paid attention to when handling:
1. Avoid direct contact with skin, eyes and respiratory tract, and avoid inhaling dust;
2. In the operation should wear personal protective equipment, such as gloves, goggles and gas masks, etc;
3. It is best to conduct the experiment in a well-ventilated laboratory to avoid toxic gases or volatiles.
Please note that when using or handling this compound, it is important to follow local safety practices and refer to the safety data sheet for the relevant chemical and the safety information provided by the supplier.
Last Update:2024-04-10 22:29:15